Nonequilibrium thermodynamics. III. Generalization of Maxwell, Clausius-Clapeyron, and response-function relations, and the Prigogine-Defay ratio for systems in internal equilibrium
نویسندگان
چکیده
منابع مشابه
Density-scaling and the Prigogine-Defay ratio in liquids.
The term "strongly correlating liquids" refers to materials exhibiting near proportionality of fluctuations in the potential energy and the virial pressure, as seen in molecular dynamics simulations of liquids whose interactions are comprised primarily of van der Waals forces. Recently it was proposed that the Prigogine-Defay ratio, Π, of strongly correlating liquids should fall close to unity....
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ژورنال
عنوان ژورنال: Physical Review E
سال: 2012
ISSN: 1539-3755,1550-2376
DOI: 10.1103/physreve.85.041129